Tetraaquabis(2-methyl-1H-imidazole-κN 3)cobalt(II) naphthalene-1,5-disulfonate
نویسنده
چکیده
In the title complex, [Co(C(4)H(6)N(2))(2)(H(2)O)(4)](C(10)H(6)O(6)S(2)), the cation and anion both reside on crystallographic inversion centers, such that the asymmetric unit comprises one half cation and one half anion. The central Co(II) ion is coordinated by four water mol-ecules and two 2-methyl-imidazole ligands, resulting in a trans-octa-hedral coordination geometry. The existence of strong N-H⋯O and O-H⋯O hydrogen-bonding inter-actions gives rise to a three-dimensional structure.
منابع مشابه
Bis[bis(1H-imidazole-κN 3)silver(I)] naphthalene-1,5-disulfonate
The title compound, [Ag(C(3)H(4)N(2))(2)](2)(C(10)H(6)O(6)S(2)), exists in the form of isolated cations and anions with electrostatic inter-action between them. The Ag atom is two-coordinated by the N atoms of two crystallographically independent imidazole mol-ecules. The naphthalene-1,5-disulfonate anion is located on a crystallographic center of symmetry. The cations and anions are connected ...
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